Synthesis and single crystal structures of n-substituted benzamides and their chemoselective selenation/reduction derivatives

Guoxiong Hua; Cameron L. Carpenter-Warren; David B. Cordes; Alexandra M.Z. Slawin; J. Derek Woollins

doi:10.3390/molecules26082367

Synthesis and single crystal structures of n-substituted benzamides and their chemoselective selenation/reduction derivatives

Guoxiong Hua
, Cameron L. Carpenter-Warren
, David B. Cordes
, Alexandra M.Z. Slawin
, J. Derek Woollins

Khalifa University

University of St Andrews

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A series of N-aryl-N-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins’ reagent, a highly efficient chemoselective selena-tion/reduction reagent, gave the corresponding N-aryl-N-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.

Original language	English
Article number	2367
Journal	Molecules
Volume	26
Issue number	8
DOIs	https://doi.org/10.3390/molecules26082367
State	Published - 2 Apr 2021

Keywords

N-Substituted Benzamides
Reduction reagent
Selenation reagent
Single crystal X-ray structures
Woollins’ reagent

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10.3390/molecules26082367

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title = "Synthesis and single crystal structures of n-substituted benzamides and their chemoselective selenation/reduction derivatives",

abstract = "A series of N-aryl-N-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins{\textquoteright} reagent, a highly efficient chemoselective selena-tion/reduction reagent, gave the corresponding N-aryl-N-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.",

keywords = "N-Substituted Benzamides, Reduction reagent, Selenation reagent, Single crystal X-ray structures, Woollins{\textquoteright} reagent",

author = "Guoxiong Hua and Carpenter-Warren, \{Cameron L.\} and Cordes, \{David B.\} and Slawin, \{Alexandra M.Z.\} and \{Derek Woollins\}, J.",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

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doi = "10.3390/molecules26082367",

language = "English",

volume = "26",

journal = "Molecules",

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T1 - Synthesis and single crystal structures of n-substituted benzamides and their chemoselective selenation/reduction derivatives

AU - Hua, Guoxiong

AU - Carpenter-Warren, Cameron L.

AU - Cordes, David B.

AU - Slawin, Alexandra M.Z.

AU - Derek Woollins, J.

PY - 2021/4/2

Y1 - 2021/4/2

N2 - A series of N-aryl-N-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins’ reagent, a highly efficient chemoselective selena-tion/reduction reagent, gave the corresponding N-aryl-N-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.

AB - A series of N-aryl-N-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins’ reagent, a highly efficient chemoselective selena-tion/reduction reagent, gave the corresponding N-aryl-N-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.

KW - N-Substituted Benzamides

KW - Reduction reagent

KW - Selenation reagent

KW - Single crystal X-ray structures

KW - Woollins’ reagent

UR - https://www.scopus.com/pages/publications/85105187341

U2 - 10.3390/molecules26082367

DO - 10.3390/molecules26082367

M3 - Article

C2 - 33921716

AN - SCOPUS:85105187341

SN - 1420-3049

VL - 26

JO - Molecules

JF - Molecules

IS - 8

M1 - 2367

ER -

Synthesis and single crystal structures of n-substituted benzamides and their chemoselective selenation/reduction derivatives

Abstract

Keywords

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