Metal-porphyrin in epoxidation of olefins: Recent advances

Irshad Ahmad; Shagufta; Sadia Rehman

doi:10.1016/j.tet.2021.132604

Metal-porphyrin in epoxidation of olefins: Recent advances

Irshad Ahmad
, Shagufta
, Sadia Rehman

American University of Ras Al Khaimah

Research output: Contribution to journal › Review article › peer-review

19 Scopus citations

Abstract

The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry.

Original language	English
Article number	132604
Journal	Tetrahedron
Volume	104
DOIs	https://doi.org/10.1016/j.tet.2021.132604
State	Published - 8 Jan 2022

Keywords

Asymmetric
Catalysis
Epoxidation
Heterogeneous
Homogeneous
Porphyrins

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10.1016/j.tet.2021.132604

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title = "Metal-porphyrin in epoxidation of olefins: Recent advances",

abstract = "The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry.",

keywords = "Asymmetric, Catalysis, Epoxidation, Heterogeneous, Homogeneous, Porphyrins",

author = "Irshad Ahmad and Shagufta and Sadia Rehman",

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year = "2022",

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doi = "10.1016/j.tet.2021.132604",

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T1 - Metal-porphyrin in epoxidation of olefins

T2 - Recent advances

AU - Ahmad, Irshad

AU - Shagufta,

AU - Rehman, Sadia

PY - 2022/1/8

Y1 - 2022/1/8

N2 - The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry.

AB - The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry.

KW - Asymmetric

KW - Catalysis

KW - Epoxidation

KW - Heterogeneous

KW - Homogeneous

KW - Porphyrins

UR - https://www.scopus.com/pages/publications/85121534263

U2 - 10.1016/j.tet.2021.132604

DO - 10.1016/j.tet.2021.132604

M3 - Review article

AN - SCOPUS:85121534263

SN - 0040-4020

VL - 104

JO - Tetrahedron

JF - Tetrahedron

M1 - 132604

ER -

Metal-porphyrin in epoxidation of olefins: Recent advances

Abstract

Keywords

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